I would have thought that would only be possible if the clay back was pigmented and a slowset or dispersion adhesive was used and grouted too soon. Can't see why it would discolour one make of grout and not another. Or even the tile was underfired and was still a bit chalky and some residue contaminated the grout?
Did see grout discolour once when the plaster behind got wet after a leak. White grout went pinky. Slighty discoloured the tiles to so maybe more to do with a dodgy background than the tile?
Who knows. Loads of reasons why grout can discolour.