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Daveyboy
From the picture, It looks like you have lifted some of the screed and if you say it came up easily with the tiles, then it has seperated from the concrete slab for some reason. There is a crack running through the concrete slab where the screed has been removed which suggests you have had some movement in the floor, sometime in the past, which may explain why the screed has seperated..make sure the rest of the screed is sound then re-screed the rest - it's quite deep for SLC unless you mix it with sand..let it dry then prime the screed and lay an uncoupling membrane over the screed before tiling..this should prevent your new tiles from cracking...