Rab, surely the method of application and drying times depend on what SLC you use, area size, thickness, environment, etc.
Personally, I think it's better to chose an SLC meant for up to 30mm thickness if that's what I need, instead of pouring, for example, three 10mm layers with an SLC meant for 10mm. That way, the uniformity of the SLC curing and density is more or less guaranteed. Applying layers can't guarantee that, especially if you pour the layers too soon after another. That can lead to serious complications with many SLCs, such as cracking and delamination of the SLC layers.
IMHO, the single best piece of advice that can be given to anyone who wants to use SLC, or any product for that matter, is to read the product specs, and instructions, and follow them. Liability you know...