Monkey,
As I said before - try the oven on a leftover tile to prove these tiles unsuitable for underfloor heating (UFH). I suggested 50C but you should check with the supplier of your underfloor heating system and ask how hot could the lower surface of your tile (as the bottom is closer to the heat source) become when it is heated with your UFH. it could be as high as 70C or 80C, with it only being 25C on the upper surface.
When you have that info from the UFH supplier, put one of those tiles in your oven for an hour at that temp and see if it's flexible. If the resins are affected, you will find that your tile is no longer brittle, and may bend or dent when hit lightly with a hammer.
If you see anything like this happening at the temperatures the UFC will put out then those tiles are conclusively not suitable for under floor heating.
Typical resins do have a softening point of anywhere from 40C to 120C, which may be in the heating range of the elements supplying the heat for UFH.