Hi and welcome to the forum Rugrat 😊
Cemfloor being a liquid screed will more than likely have layer of laitence on top, this must be removed.
This can normally done with a floor scrubber with a 60# copper disc.
It presents as a scum on top of the screed, although a lot of screed companies now claim that their liquid screeds are either low or no laitence finish.
It’s a very dusty job without correct dust extraction equipment, ensure area is well ventilated and masks are worn.
Although most hired sanding equipment is supplied with dust extraction equipment, check before hand.
Vacuum and prime post sanding.
This is a cemfloor, two images, one before and after sanding.
Make sure the ufh has been commissioned correctly first. (Taken thro heating cycle)
Being a natural stone a antifracture mat or decoupling membrane would normally be advised on top of the screed.
Once installed, the heating cycle should be repeated 28 days after install prior to normal use.
It takes 28 days for the adhesive to cure.
This will help prevent thermal shock.
This is quite a challenge for a DIY tiler, good luck.